一维链状冠醚配合物:[Na(18-C-6)]2[Zn(mnt)2]的合成与晶体结构OA
One-dimensional Chain Crown Ether Complexes. Synthesis and Crystal Structure of 18-Crown- 6 Complex: [Na(18-Crown-6)]2 [Zn(mnt)2]
研究了18冠6与Na2[Zn(mnt)2]的反应,并通过元素分析、红外光谱、单晶X-射线衍射对生成的配合物[Na(18-C-6)]2[Zn(mnt)2]进行了表征.配合物为单斜晶系,空间群C2/c.晶体学数据:a=2.2418(6),b=1.1359(3),c=1.9887(6)nm,β=120.391(4)°,V=4.368(2)nm3,Z=4,Dcalcd=1.399g/cm3,F(000)=1 920,R1=0.0362,wR2=0.056…查看全部>>
The novel complex [Na(18-C-6)]2[Zn(mnt)2](1) was characterized by elemental analysis, IR spectrum and X-ray diffraction analysis. 1 beolngs to monoclinic,space group C2/c with cell dimensions:a=2. 241 8(6),b=1. 1359(3),c=1. 9887(6) nm , β=120. 391(4)',V=4.368(2) nm3,Z=4,Dcalcd=1.399g/cm3,F(000)=1920,wR1=0.0362,wR2=0.0560. The complex display an one-dimensional chain of [Na(18-C-6)]+complex cations and[Zn(mnt)2]2- complex anion bridged by Na…查看全部>>
于清江;窦建民;李大成;王大奇;钟宝运
聊城师范学院,化学化工学院,山东,聊城,252000聊城师范学院,化学化工学院,山东,聊城,252000聊城师范学院,化学化工学院,山东,聊城,252000聊城师范学院,化学化工学院,山东,聊城,252000聊城师范学院,化学化工学院,山东,聊城,252000
化学化工
一维链,冠醚,18冠6,锌配合物,晶体结构
one-dimensional chain,crown ether,18-crown-6,Zn complex,crystal structure
《聊城大学学报（自然科学版）》 2001 (4)
10-11,22,3
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