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Investigating the Microstructure of Slenderized Wool Fibers at Different Stretching Ratios by Raman Spectroscopy

LIU Hong-ling YU Wei-dong ZHANG Yue-ting

东华大学学报(英文版)2005,Vol.22Issue(1):102-105,4.
东华大学学报(英文版)2005,Vol.22Issue(1):102-105,4.

Investigating the Microstructure of Slenderized Wool Fibers at Different Stretching Ratios by Raman Spectroscopy

Investigating the Microstructure of Slenderized Wool Fibers at Different Stretching Ratios by Raman Spectroscopy

LIU Hong-ling 1YU Wei-dong 1ZHANG Yue-ting2

作者信息

  • 1. College of Textiles, Donghua University, Shanghai 200051
  • 2. College of Material Science & Engineering, Donghua University, Shanghai 200051
  • 折叠

摘要

Abstract

The molecular conformation and the microstructure of the slenderized wool fibers have been studied by the Raman spectroscopy. The typical bands analyzed in this paper include the amideⅠand amide Ⅲ regions, the C-C skeletal vibration region, and the S-S and C-S bond vibration regions. The experimental results show that ⅰ) the Raman spectroscopy can reveal the secondary structural transformation from α-helical to β-pleated sheet begin at the early stage of stretching; ⅱ) the stretching mechanism of wool fibers can be divided into two different mechanisms, I.e. The secondary structural transformation and the slippage of the polypeptide chain; and ⅲ) the stretching leads to the increasing of the amount of the disordered conformation and the decreasing of the amount of S-S bonds.

关键词

Microstructure/Raman spectroscopy/wool/fiber/stretching

Key words

Microstructure/Raman spectroscopy/wool/fiber/stretching

引用本文复制引用

LIU Hong-ling,YU Wei-dong,ZHANG Yue-ting..Investigating the Microstructure of Slenderized Wool Fibers at Different Stretching Ratios by Raman Spectroscopy[J].东华大学学报(英文版),2005,22(1):102-105,4.

东华大学学报(英文版)

1672-5220

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