人工晶体学报2007，Vol.36Issue(5)：1035-1038,4.
微孔氟化磷酸镓Ga3P3O12F·0.5(1,8-C8H22N2)的水热自组装与晶体结构
Self-assembly and Crystal Structure of Microporous Fluorogallophosphate Ga3P3O12F·0.5( 1,8-C8H22N2) under Hydrothermal Conditions
摘要
Abstract
A three-dimensional microporous fluorogallophosphate Ga3P3O12F·0.5(1,8-C8H12N2)(named Hit-6) was synthesized from self-assembly of simple mixture under the mild hydrothermal conditions. The molar ratio of the initial raw mixture was GaOOH:H3PO4:HF:1 8-diaminooctane:H2O = 1:2:1:1:555.The 3-D anionic framework of Hit-6 is constructed from Ga3P3 hexamer structural units. Ga3P3 structural units are linked by vertex-sharing to form a 3-D nanoporous material with 8-ring channels along the [101]direction.关键词
水热合成/微孔/氟化磷酸镓/晶体结构Key words
hydrothermal synthesis/ microporous/fluorogallophosphate/ crystal structure分类
数理科学引用本文复制引用
杨玉林,胡伟,刘新荣,李琳,姜兆华..微孔氟化磷酸镓Ga3P3O12F·0.5(1,8-C8H22N2)的水热自组装与晶体结构[J].人工晶体学报,2007,36(5):1035-1038,4.基金项目
The project supported by the National Natural Science Foundation of China( No. 20671025 ) （ No. 20671025 ）
Department of Education Foundation of Heilongjiang Province(No.10551335) （No.10551335）
the Natural Science Foundation of Heiloogjiang Province (No. 13200603) （No. 13200603）
Harbin Science and Technolongy Bureau Foundation of China(No.2005AFXXJ034) （No.2005AFXXJ034）
