安徽大学学报（自然科学版）2000，Vol.24Issue(3)：104-110,7.
含C60高分子材料的制备和新颖的光学性能的研究
Preparation and Novel Optical Properties of Fullerene- based Polymer Materials
摘要
Abstract
Synthesis of fullerenc polymers has stimulated great interests of polymer scientists because suitably-designed fullerene polymers would be well processable and may also exhibit novel properties which are superior to those of the parent forms. Many different kinds of fullerone functionalized polymers have been prepared. In the letter, we prepared C60 and phenylacetylene copolymers with C60 content of 4.6 wt% and 9.6 wt% using organic metallic catalyst. Their structure were characterized using GPC, FTIR, NMR and UV spectrometer, respectively. The copolymers effectively limit strong 532- nm laser pulses. A new blue fluorescence with an emission peak wavelength at ca. 470 nm in the copolymers was found when the copolymers were excited at the wavelength of ca. 400 nm and its intensity increases with more C60 in the copolymers.关键词
C60/功能高分子/聚炔/光限幅/光致发光Key words
C60/functional polymer/polyacetylene/optical limiter/photoluminescence引用本文复制引用
徐洪耀,光善仪,李村,易佑民,唐本忠..含C60高分子材料的制备和新颖的光学性能的研究[J].安徽大学学报（自然科学版）,2000,24(3):104-110,7.基金项目
Supported by National Natural Science Foundation (No. 29804001) and the Key Foundation Project of Anhui Province (No. 9722009) and Natural Science Foundation of Educational Committee of Anhui Province (99JL0015). （No. 29804001）
