中山大学学报(自然科学版)2004,Vol.43Issue(6):109-112,4.
三氟甲基磺酸银与1,4-二咪唑基二甲苯(bix)在双膦配体参与下的自组装:零维金属大环配合物或二维配位的聚合物
Self-assembly of Silver Triflate and 1,4-Bis (imidazol- 1-yl) Xylene (bix) in the Presence of A Diphosphine:Discrete Metallomacrocycle Versus 2D Coordination Polymer
摘要
Abstract
Assembly of silver triflate with 1,40-bis (imidazol-1-yl)exlene in the presence of a diphosphine Ph2P (CH2)n PPh2 (n=1 or 2) provided complexes [Ag4 (bix)2 (dppm)4 (CF3SO3)2]·2DMF·2H2O and [Ag (bix) (dppe)]n(2) (CF3SO3)n·nDMF·nCH3OH,where the cation 1 is a discrete 34-membered metallomacrocycle and 2 a polymeric 2D (4,4) grid network.The backbone (CH2)n of the diphsophine obviously plays the major role in the varied architectures.关键词
银(Ⅰ)配合物/1,4-二咪唑基-二甲苯/双膦配体/晶体结构/电喷雾-质谱Key words
silver (Ⅰ) complex/1,4-bis (imidazol-1-yl)xylene/diphosphine/crytal structure/ESI-MS分类
化学化工引用本文复制引用
吕兴强,张利,陈春龙,谭海燕,康北笙..三氟甲基磺酸银与1,4-二咪唑基二甲苯(bix)在双膦配体参与下的自组装:零维金属大环配合物或二维配位的聚合物[J].中山大学学报(自然科学版),2004,43(6):109-112,4.基金项目
国家自然科学基金资助项目(200273085) (200273085)
高等学校博士学科点专项科研基金资助项目(20020558027) (20020558027)