感光科学与光化学2001，Vol.19Issue(2)：109-115,7.
ABO3钙钛矿型复合氧化物光催化活性与B离子d电子结构的关系
THE RELATION OF PHOTOCATALYTIC ACTIVITY OF PEROVSKTIE (ABO3) TYPE OXIDE AND D-ELECTRON STRUCTURE OF ION B
桑丽霞 1傅希贤 1白树林 1杨秋华 1王俊珍 1曾淑兰1
作者信息
摘要
Abstract
The d-electron structure of ion B in perovskite(ABO3) type oxide has the key role on the binding energy of B-O and the charge-transfer energy(ΔCT) between O2p and B3d, so it has an important influence on the photocatalytic activity of ABO3. In this paper, the species LaBO3(B=Ti-Co) were prepared by the mixed oxide method and the citrate complex method. By analyzing the photocatalytic degradation experiment and their photo-acoustic spectra, the results show that photocatalytic activity of LaBO3 increases with the increasing of d-electron number of ion B.关键词
钙钛矿型复合氧化物/光催化活性/d电子结构/电荷转移能ΔCT分类
化学化工引用本文复制引用
桑丽霞,傅希贤,白树林,杨秋华,王俊珍,曾淑兰..ABO3钙钛矿型复合氧化物光催化活性与B离子d电子结构的关系[J].感光科学与光化学,2001,19(2):109-115,7.
