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Effect of Cu2+ concentration on hydrogen fermentation by mixed culture

任南琪 丁杰 丁兰 刘敏 李永峰 包红旭

哈尔滨工业大学学报(英文版)2004,Vol.11Issue(1):11-16,6.
哈尔滨工业大学学报(英文版)2004,Vol.11Issue(1):11-16,6.

Effect of Cu2+ concentration on hydrogen fermentation by mixed culture

Effect of Cu2+ concentration on hydrogen fermentation by mixed culture

任南琪 1丁杰 1丁兰 1刘敏 2李永峰 1包红旭1

作者信息

  • 1. School of Municipal and Environmental Engineering,Harbin Institute of Technology,Harbin 150090,China
  • 2. College of Chemistry,Jilin University,Changchun 130023,China
  • 折叠

摘要

Abstract

The results of the study on the effect of Cu2+ concentration on hydrogen production using a glucose solution and mixed microorganisms from a 9.2 L laboratory-scale digester operated at 35 ℃ indicated the productions of hydrogen, volatile fatty acids (VFAs), ethanol and biogas were inhibited by the added Cu2 + which caused a reduction in the glucose degradation efficiency. The specific yields of hydrogen, ethanol and acetate decreased with increased Cu2+ concentration in the mixed microorganisms. When the Cu2 + concentration in the mixed microorganisms was almost an constant, the specific yields of hydrogen, ethanol and acetate were very similar. A 50% inhibition of hydrogen yield (ECso) occurred at a Cu2+ dosage of 0. 50 mg/L in the present investigation. Cu2+ in the external environment is accumulated in the mixed microorganisms. The Cu2 + speciation, using a sequential extraction technique, showed that the Cu2+ was present mainly bound to organic sites in the mixed microorganisms in the present investigation.

关键词

hydrogen fermentation/anaerobic digestion/Cu2+/volatile fatty acids

Key words

hydrogen fermentation/anaerobic digestion/Cu2+/volatile fatty acids

分类

资源环境

引用本文复制引用

任南琪,丁杰,丁兰,刘敏,李永峰,包红旭..Effect of Cu2+ concentration on hydrogen fermentation by mixed culture[J].哈尔滨工业大学学报(英文版),2004,11(1):11-16,6.

基金项目

Sponsored by" 973" Fundamental Science Program of China ( Grant No. G2000026402 ) and "863" Project of China ( Grant No. 2001 AA515030). ( Grant No. G2000026402 )

哈尔滨工业大学学报(英文版)

1005-9113

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