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The Effect of Casting Solvent on the Electrical Property of Polyaniline/Polyacrylonitrile

东华大学学报(英文版)2006,Vol.23Issue(1):117-120,4.
东华大学学报(英文版)2006,Vol.23Issue(1):117-120,4.

The Effect of Casting Solvent on the Electrical Property of Polyaniline/Polyacrylonitrile

The Effect of Casting Solvent on the Electrical Property of Polyaniline/Polyacrylonitrile

1

作者信息

  • 1. State Key Laboratory of Modification Chemical Fibers and Polymer Materials, Donghua University, Shanghai 200051;Department of material and chemical Engineering, Zhongyuan Institute of Technology, Zhengzhou 450007;State Key Laboratory of Modification Chemical Fibers and Polymer Materials, Donghua University, Shanghai 200051;State Key Laboratory of Modification Chemical Fibers and Polymer Materials, Donghua University, Shanghai 200051;State Key Laboratory of Modification Chemical Fibers and Polymer Materials, Donghua University, Shanghai 200051
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摘要

Abstract

Blends of dodecylbenzene sulfonic acid doped polyaniline (PANI-DBSA) and polyacrylonitrile (PAN) dissolved in either CHCl3/DMF or CHCl3/DMSO mixture were solution cast. The conductivity of the blends with various compositions was measured and the doped cxtent of PANIDBSA in different casting solvent systems was studied.Solution blends prepared from CHCl3/DMSO displayed higher conductivity than those obtained via CHCl3/DMF.The dedoping reaction of PANI-DBSA in CHCl3/DMF identified by UV-Vis and FTIR analysis contributed to the lower conductivity of PANI-DBSA/PAN blend.

关键词

polyaniline/polyacrylonitrile/casting solvent/electrical property

Key words

polyaniline/polyacrylonitrile/casting solvent/electrical property

分类

矿业与冶金

引用本文复制引用

..The Effect of Casting Solvent on the Electrical Property of Polyaniline/Polyacrylonitrile[J].东华大学学报(英文版),2006,23(1):117-120,4.

东华大学学报(英文版)

1672-5220

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