株洲工学院学报2000，Vol.14Issue(3)：1-2,2.
二苯甲烷-4，4′-二异氰酸酯的非光气合成法
Synthesis of 4,4′-Diphenylmethane Diisocyanate Bis(trichloromethly)Carbonate
夏敏 1汤建新1
作者信息
- 1. 株洲工学院包装新材料与技术重点实验室湖南株洲 412008
- 折叠
摘要
Abstract
Bis(trichlormethyl)carbonate as the phosgene substitute in the preparation of 4,4′-diphenylmethane diisocyanate is introduced. The reaction is carried out at room temperature for 2 hours under the stoichiometric ratio of substrates. Besides,the influence of PH value on the yields of products is discussed,fmding optimum PH within 11～12.关键词
二(三氯甲基)碳酸酯/羰基化反应/二苯甲烷-4,4′-二异氰酸酯Key words
bis(trichloromethyl) carbonate/carbonlation/4,4′-diphenylmethane diisocyanate分类
化学化工引用本文复制引用
夏敏,汤建新..二苯甲烷-4，4′-二异氰酸酯的非光气合成法[J].株洲工学院学报,2000,14(3):1-2,2.
