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Study on the Ion Association in PVdF-based Gel Polymer Electrolyte

东华大学学报(英文版)2006,Vol.23Issue(1):121-124,4.
东华大学学报(英文版)2006,Vol.23Issue(1):121-124,4.

Study on the Ion Association in PVdF-based Gel Polymer Electrolyte

Study on the Ion Association in PVdF-based Gel Polymer Electrolyte

1

作者信息

  • 1. Institute of Macromolecules and Bioengineering, North University of China, Taiyuan 030051;State Key Laboratory for Modification of Chemical Fiber and Polymer Materials, College of Materials Science and Engineering,Donghua University, Shanghai 200051;State Key Laboratory for Modification of Chemical Fiber and Polymer Materials, College of Materials Science and Engineering,Donghua University, Shanghai 200051
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摘要

Abstract

Gel polymer electrolytes based on the poly (vinylidene fluoride) (PVdF) and the electrolyte of LiClO4 in propylene carbonate (PC) were prepared by the solution casting technique. The ionic conductivity of the gel electrolytes was concentration of lithium salt. Because of the strong coulombiq attractions, the dissolved salt ions might aggregate into ion pairs and multiple ion aggregates. The analysis of DSC and X-ray diffraction revealed that the ions association occurred at higher concentration of lithium salt.

关键词

gel polymer electrolyte/PVdF/ion association/conducitvity

Key words

gel polymer electrolyte/PVdF/ion association/conducitvity

分类

化学化工

引用本文复制引用

..Study on the Ion Association in PVdF-based Gel Polymer Electrolyte[J].东华大学学报(英文版),2006,23(1):121-124,4.

东华大学学报(英文版)

1672-5220

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