物理化学学报2004,Vol.20Issue(10):1216-1220,5.
对甲苯磺酸铜的电化学表征
Electrochemical Characterization of Copper Paratolylsulfonate
摘要
Abstract
Copper(Ⅱ) paratolylsulfonate [Cu( p-OTs ) ]2 has been synthesized and characterized by X-ray crystal structure analysis. The electrochemical parameters of Cu(p-OTs)2 in H2O, CH3OH and DMF have been studied on platinum electrode, respectively. Different reaction mechanisms in different solvents are found. The electrochemical reduction of Cu(Ⅱ) to Cu proceeds by two one-electron steps in H2O. However, it is a one two-electron process in CH3OH and DMF.关键词
对甲苯磺酸铜/电化学/循环伏安法/模拟酶Key words
Copper paratolylsulfonate/Electrochemistry/Cyclic voltammetry/Mimetic enzyme分类
化学化工引用本文复制引用
宋继国,沈培康..对甲苯磺酸铜的电化学表征[J].物理化学学报,2004,20(10):1216-1220,5.基金项目
国家高技术研究发展规划(863项目2003AA517050)和广州科技基金(2003Z2-D0081)资助项目 (863项目2003AA517050)