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有机电致发光材料用N,N,N′,N′-四苯基联苯二胺类化合物的制备

柴生勇 安忠维

液晶与显示2001,Vol.16Issue(2):124-128,5.
液晶与显示2001,Vol.16Issue(2):124-128,5.

有机电致发光材料用N,N,N′,N′-四苯基联苯二胺类化合物的制备

Preparation of N, N, N′N′- Tetraphenylbiphenyldiamines for Organic Electroluminescent Device as Hole Transport Materials

柴生勇 1安忠维2

作者信息

  • 1. 西安瑞联近代电子材料有限责任公司, 陕西 西安 710065
  • 2. 西安近代化学研究所, 陕西 西安 710065 E-mail:csy2048@pub.xaonline.com
  • 折叠

摘要

Abstract

The tetraphenylbiphenyldiamines used as the hole transport materials have great application potentiality in organic electroluminescent(OEL) devices. Three of these compounds were prepared by Ulmann reaction .They were N, N′-diphenyl-N, N′-bis(3-methylphenyl)-[1, 1′-biphenyl]-4, 4′-diamine(1) , N, N′-diphenyl-N, N′-bis(4-methylphenyl)-[1, 1′-biphenyl]-4, 4′-diamine(2) and N, N, N′, N′-tetraphenyl-[1, 1′-biphenyl]-4, 4′-diamine(3). The method of seperating products from the reaction mixtures was improved, and the yields and purities are (1)Y 85%,P97.6% ;(2)Y95%, P 98.5% and (3)Y 70%, 98.1%, respectively. Their IR spectra were all measured also

关键词

制备/四苯基二胺化合物/空穴传输材料/有机电致发光

Key words

preparation/tetraphenylbiphenyldiamines/hole transport material/organic electroluminescence

分类

信息技术与安全科学

引用本文复制引用

柴生勇,安忠维..有机电致发光材料用N,N,N′,N′-四苯基联苯二胺类化合物的制备[J].液晶与显示,2001,16(2):124-128,5.

液晶与显示

OACSCD

1007-2780

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