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超临界乙醇流体制备TiO2光催化剂(Ⅰ)合成与光催化性能

黄彪

化工学报2003,Vol.54Issue(9):1315-1318,4.
化工学报2003,Vol.54Issue(9):1315-1318,4.

超临界乙醇流体制备TiO2光催化剂(Ⅰ)合成与光催化性能

PREPARATION OF PHOTO-CATALYTIC TiO2 BY SUPERCRITICAL ETHANOL (Ⅰ) SYNTHESIS AND PHOTOCATALYSIS

黄彪1

作者信息

  • 1. 福建农林大学材料工程学院,福建,南平,353001
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摘要

Abstract

Photo-catalytic TiO2 was prepared from tetraisopropyl titanate (TPT) in supercritical ethanol. It was found that TPT in supercritical ethanol could be effectively converted into the anatase-form of TiO2 crystallites. The anatase-form of TiO2 as a photo-catalyst was evaluated for its adsorptivity and subsequent photo-catalytic activities on formaldehyde, one of the harmful air pollutants in the environment. As a result, the supercritically treated TiO2 had a high decomposing ability. Under the same condition, the experiment was repeated for 5 times,and photocatalysis of the samples did not decrease. This indicated that the supercritical treatment was effective to prepare photo-catalytic TiO2, which was feature by stability, longevity and high photo-catalytic decomposition of formaldehyde for environmental cleaning. Meanwhile, unlike conventional chemical reaction, which is complex and time-consuming, supercritical treatment is easy to operate, saving both time and labor.

关键词

甲醛 超临界乙醇 TiO2 光催化活性

Key words

formaldehyde, supercritical ethanol, TiO2, photo-catalytic activity

分类

化学化工

引用本文复制引用

黄彪..超临界乙醇流体制备TiO2光催化剂(Ⅰ)合成与光催化性能[J].化工学报,2003,54(9):1315-1318,4.

基金项目

国家留学基金资助项目. ()

化工学报

OA北大核心CSCDCSTPCD

0438-1157

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