武汉化工学院学报2001，Vol.23Issue(1)：1-4,11,5.
富CO合成气三相床甲醇合成过程研究
Influences of main reaction factors on methanol synthesis process utilizing COrich syngas
王存文 1丁百全 2朱炳辰2
作者信息
- 1. 武汉化工学院化工系
- 2. 华东理工大学化工系
- 折叠
摘要
Abstract
Influences of main reaction factors on liquidphase methanol synthesis process were studied in a wellmixed stirred slurry reactor under COrich condition. The experimental results show that methanol productivity and CO conversion increase with the reaction temperature and pressure, and that with feed rate increasing methanol productivity also increases whereas CO conversion decreases. To be convenient for analyzing to effects of mass transfer, a conception of quasiintrinsic kinetics of threephase methanol synthesis process was put forward in this paper. By comparing the quasiintrinsic kinetics obtained in this work with gassolid twophase methanol synthesis, it was found that the threephase methanol synthesis process is much less dependent on the temperature and the pressure than the twophase system. In additions to, it turns out that C302 type copperbased catalyst can well be applied for liquidphase methanol synthesis process under the condition of COrich syngas.关键词
三相床甲醇合成/富CO合成气/温度与压力效应/准本征动力学分类
化学化工引用本文复制引用
王存文,丁百全,朱炳辰..富CO合成气三相床甲醇合成过程研究[J].武汉化工学院学报,2001,23(1):1-4,11,5.
