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首页|期刊导航|波谱学杂志|2D NMR对栌菊木中的一个倍半萜内酯进行结构解析

2D NMR对栌菊木中的一个倍半萜内酯进行结构解析

胡晓玉 吴新卫 梅娜 周乐

波谱学杂志2007,Vol.24Issue(2):141-146,6.
波谱学杂志2007,Vol.24Issue(2):141-146,6.

2D NMR对栌菊木中的一个倍半萜内酯进行结构解析

Structure Determination of a Sesquiterpene Lactone Isolated from Nouelia insignis Franch by 2D NMR

胡晓玉 1吴新卫 2梅娜 1周乐1

作者信息

  • 1. 西北农林科技大学,陕西,杨凌,712100
  • 2. 中国科学院,成都生物研究所,四川,成都,610041
  • 折叠

摘要

Abstract

A sesquiterpene lactone was isolated from Nouelia insignis Franch,and its structure was elucidated(compound 1)by 2D NMR to be 8β,9-dihydro-onoseriolide.Complete assignment of the 1H and 13C chemical shifts for the compound was obtained.The assignments of H1 and H-2 of the compound previously reported were found incorrect,and the correct assignments were given.The results of this study may have some practical significance for the structural elucidation of onoseriolide sesquiterpene lactones.

关键词

NMR/化学位移归属/乌药烷型/栌菊木

Key words

NMR/chemical shift assignment/onoseriolide/Nouelia insignis Franch

分类

化学化工

引用本文复制引用

胡晓玉,吴新卫,梅娜,周乐..2D NMR对栌菊木中的一个倍半萜内酯进行结构解析[J].波谱学杂志,2007,24(2):141-146,6.

波谱学杂志

OA北大核心CSCDCSTPCD

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