波谱学杂志2007,Vol.24Issue(2):141-146,6.
2D NMR对栌菊木中的一个倍半萜内酯进行结构解析
Structure Determination of a Sesquiterpene Lactone Isolated from Nouelia insignis Franch by 2D NMR
胡晓玉 1吴新卫 2梅娜 1周乐1
作者信息
- 1. 西北农林科技大学,陕西,杨凌,712100
- 2. 中国科学院,成都生物研究所,四川,成都,610041
- 折叠
摘要
Abstract
A sesquiterpene lactone was isolated from Nouelia insignis Franch,and its structure was elucidated(compound 1)by 2D NMR to be 8β,9-dihydro-onoseriolide.Complete assignment of the 1H and 13C chemical shifts for the compound was obtained.The assignments of H1 and H-2 of the compound previously reported were found incorrect,and the correct assignments were given.The results of this study may have some practical significance for the structural elucidation of onoseriolide sesquiterpene lactones.关键词
NMR/化学位移归属/乌药烷型/栌菊木Key words
NMR/chemical shift assignment/onoseriolide/Nouelia insignis Franch分类
化学化工引用本文复制引用
胡晓玉,吴新卫,梅娜,周乐..2D NMR对栌菊木中的一个倍半萜内酯进行结构解析[J].波谱学杂志,2007,24(2):141-146,6.