燃料化学学报2001，Vol.29Issue(2)：144-148,5.
Zr、Mo、Zn添加剂及机械球磨对钒-磷-氧催化剂性质的影响
EFFECTS OF Zr, Mo AND Zn ADDITIVES AND PHYSICAL MILLING ON
THE PROPERTIES OF VPO CATALYSTS
王晓书 1季伟捷 2许利军 2颜其洁 2陈懿2
作者信息
- 1. 南京大学化学化工学院,南京大学现代分析中心,
- 2. 南京大学化学化工学院,
- 折叠
摘要
Abstract
Effect of Zr, Mo and Zn additives and physical milling on the properties of VPO catalysts have been investigated by means of XRD, XPS and FT-IR. Addition of Mo and Zn decreased the relative exposure of (200) plane, however, the relative concentration of the surface V4+ increased, therefore, the catalytic performance was increased. Addition of Zr appeared to increase the surface P/V ratios of the catalysts, and the element V on the surface was substiruted by Zr, so that Zr component showed insignificant promoting effect. Physical milling process increased the relative exposure of (200) plane, and the catalytic performance was enhanced.关键词
VPO催化剂/机械球磨/添加剂/XPS/XRD分类
化学化工引用本文复制引用
王晓书,季伟捷,许利军,颜其洁,陈懿..Zr、Mo、Zn添加剂及机械球磨对钒-磷-氧催化剂性质的影响[J].燃料化学学报,2001,29(2):144-148,5.
