利用核磁共振研究准轮烷的振荡行为OA北大核心CSCD
NMR STUDIES OF PSEUDOROTAXANES
利用含巯基苯醚链和含羟基苯醚链分别与缺电子联吡啶大环化合物CPQT形成准轮烷，并利用变温核磁共振技术研究了准轮烷的振荡行为.
Two new type pseudorotaxanes are formed by novel (-electron-rich aromatic polyethers containing hydroxy and thiohydroxy with cyclobis(paraquat-phenylene)tetracationic cyclophane(CPQT) respectively. We use 1H NMR spectroscopy to study the property of pseudorotaxanes, and found that the pseudorotaxane containing hydroxy is more stable than the pseudorotaxane containing thiohydoxy as a result of ［C-H…OH］ hydrogen bonds. Otherwise, we can monitor the pseudorotax…查看全部>>
席海涛;孙小强;杨扬
Key Laboratory of Fine Petrochemical Engineering, Jiangsu Institute of Petrochemical Technology,Key Laboratory of Fine Petrochemical Engineering, Jiangsu Institute of Petrochemical Technology,Key Laboratory of Fine Petrochemical Engineering, Jiangsu Institute of Petrochemical Technology,
数理科学
核磁共振准轮烷超分子
《波谱学杂志》 2001 (2)
149-153,5
教育部“高等学校骨干教师资助计划”
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