高等学校化学学报2000，Vol.21Issue(10)：1527-1529,3.
噻吩甲酰三氟丙酮-酰基吡唑啉酮-邻菲咯啉合铕(Ⅲ)四元配合物的合成和表征
Synthesis and Characteristics of Thienyitrifluroacetone acyl pyrazolone-phenanthrol ine-europium Chelate
摘要
Abstract
A novel chelate Eu(TTA)2(PMTBBP)Phen, which contained ligand 1-pheny-3-methyl-4-(4′-t-butylbenzoyl)-5-pyrazolone (HPMTBBP), 4,4,4-trifluro-1-(2-thienyl)-1, 3-butandione (HTTA) and phenanthroline(Phen), was synthesized. Its chemical structure was elucidated by IR, UV, 1H NMR,MS, DSC and elementary analysis. The influence of acylpyrazolone on fluorescent intensity of the new chelate was studied. The results showed that Eu (TTA)2 (PMTBBP)Phen had more excellent PL properties and better film formation than that of Eu(TTA)3Phen.关键词
铕配合物/合成/酰基吡唑啉酮/荧光特性Key words
Europium complex/Synthesis/Acylpyrazolone/Fluorescent property分类
化学化工引用本文复制引用
朱卫国,苑同锁,魏孝强,卢志云,黄艳,刘煜,谢明贵..噻吩甲酰三氟丙酮-酰基吡唑啉酮-邻菲咯啉合铕(Ⅲ)四元配合物的合成和表征[J].高等学校化学学报,2000,21(10):1527-1529,3.基金项目
国家自然科学基金(批准号：29972032)资助. （批准号：29972032）
