核化学与放射化学2001，Vol.23Issue(1)：1-6,6.
乙异羟肟酸的合成及其与Pu(Ⅳ)，Np(Ⅳ)配合物稳定常数的测定
SYNTHESIS OF ACETOHYDROXAMIC ACID AND DETERMINATION OF STABILITY CONSTANTS OF ITS COMPLEXES WITH Pu(Ⅳ) AND Np(Ⅳ)
郑卫芳 1常志远1
作者信息
- 1. 中国原子能科学研究院放射化学研究所，北京 102413
- 折叠
摘要
Abstract
Acetohydroxamic acid (AHA) is synthesized by the method ofhydrochloric hydroxylamine reaction with acetic ether in alcohol-water medium and its structure is characterized by element analysis, IR, MS, et al. The stability constants of AHA complexes with Pu(Ⅳ) and Np(Ⅳ) have been determined in 1 mol/L nitric acid solution by TTA extraction method. The value of stability constant β1 is 5.3×1012 and 6.1×1011, respectively.关键词
乙异羟肟酸/Pu(Ⅳ)/Np(Ⅳ)/配合/稳定常数分类
化学化工引用本文复制引用
郑卫芳,常志远..乙异羟肟酸的合成及其与Pu(Ⅳ)，Np(Ⅳ)配合物稳定常数的测定[J].核化学与放射化学,2001,23(1):1-6,6.
