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抗坏血酸在α-环糊精掺杂纳米碳管涂层电极上的伏安行为

肖素芳 王宗花 王义明 罗国安

青岛大学学报(自然科学版)2002,Vol.15Issue(4):1-6,6.
青岛大学学报(自然科学版)2002,Vol.15Issue(4):1-6,6.

抗坏血酸在α-环糊精掺杂纳米碳管涂层电极上的伏安行为

VOLTAMMETRIC BEHAVIOR OF ASCORBIC ACID AT α-CYCLODEXTRIN INCORPORATED CARBON NANOTUBES-COATED ELECTRODE

肖素芳 1王宗花 2王义明 1罗国安2

作者信息

  • 1. 清华大学化学系,北京,100084
  • 2. 青岛大学化学系,青岛 266071
  • 折叠

摘要

Abstract

α-Cyclodextrin incorporated carbon nanotubes-coated electrode was fabricated and was applied to the electrocatalytic oxidation of ascorbic acid, reducing the overpotential by about 280 mV with an obviously increased current response. Basically, we would firstly like to capitalize on the best properties of the two components of the system, such as the electronic and catalytic properties of carbon nanotubes and the molecular recognition ability of α-Cyclodextrin. Characteristics of a supermolecular inclusion complex between α-Cyclodextrin and ascorbic acid were examined. A differential pulse voltammetric technique for measurement of ascorbic acid over the range of 2.5×10-6 to 1.0×10-3 mol*dm-3 has been developed.

关键词

α-环糊精/纳米碳管涂层电级/超分子络合物/抗坏血酸

Key words

α-Cyclodextrin/carbon nanotubes-coated electrode/supermolecular inclusion complex/ascorbic acid

分类

化学化工

引用本文复制引用

肖素芳,王宗花,王义明,罗国安..抗坏血酸在α-环糊精掺杂纳米碳管涂层电极上的伏安行为[J].青岛大学学报(自然科学版),2002,15(4):1-6,6.

基金项目

The authors gratefully acknowledge financial support from the National Natural Science Foundation of China (Grant No. 20075015). (Grant No. 20075015)

青岛大学学报(自然科学版)

1006-1037

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