应用化学2001，Vol.18Issue(2)：161-162,2.
双核钒酰腙配合物[VO(C14H1oN202]2(μ-O)的合成与表征
Synthesis and Characterization of Dinuclear Vanadyl Hydrazone Complex [VO(C14H10N202) ]2(μ-O)
高山 1刘世雄2
作者信息
- 1. 福州大学化学系
- 2. 黑龙江大学化学化工学院
- 折叠
摘要
Abstract
The dinuclear complex [VO (L)]2 (μ-O) (HL = salicylaldehyde benzoylhydrazone) was synthesized and characterized by elemental analysis, IR, UV, cyclic voltammetry. The results showed that two oxygen atoms and one nitrogen atom of the tridentate hydrazone ligand are coordinated to vanadium(Ⅴ) atom. The vanadium atom approximates to a distorted square pyramidal coordination sphere. The redox potentials of the title complex in different solvents follow the order:CH2Cl2＜CH3CN＜DMF.关键词
钒酰配合物.腙/合成/氧化还原性质分类
化学化工引用本文复制引用
高山,刘世雄..双核钒酰腙配合物[VO(C14H1oN202]2(μ-O)的合成与表征[J].应用化学,2001,18(2):161-162,2.
