高等学校化学学报2001，Vol.22Issue(1)：16-20,5.
四(对-癸酰氧基)苯基卟啉过渡金属配合物的合成及红外光声光谱解析
Synthesis of Tetra(4-n-decanoyloxyphenyl)porphyrin Complexes and Fourier Transform Infrared Photoacoustic Spectra
柳巍 1师同顺 1安庆大 2杨大智2
作者信息
- 1. 吉林大学化学系,
- 2. 大连理工大学材料科学与工程系,
- 折叠
摘要
Abstract
Six complexes of tetra (4-n-octanoyloxyphenyl)porphyins with Mn(Ⅲ),Fe(Ⅲ),Co(Ⅱ),Ni(Ⅱ),Cu(Ⅱ) and Zn(Ⅱ) have been synthesized in mixed solvents CH2Cl2＋DMF.The complexes were determined by elemental analysis,UV-Vis,FTIR photoacoustic spectrum,1H NMR and molar conductivity measurement.The domains of stability and the structure of the liquid crystalline phases are determined by optical microscopy and differential scanning calorimerials (DSC).The fourier transform infrared photoacoustic spectra of TDPPH2 and its complexes in the range of 3 600－190 cm-1 were measured and investigated.关键词
四(对-癸酰氧基)苯基卟啉/配合物/卟啉液晶/红外光声光谱分类
化学化工引用本文复制引用
柳巍,师同顺,安庆大,杨大智..四(对-癸酰氧基)苯基卟啉过渡金属配合物的合成及红外光声光谱解析[J].高等学校化学学报,2001,22(1):16-20,5.
