新型炭材料2005,Vol.20Issue(1):1-7,7.
石油沥青基炭纤维的制备
Carbon fibers from petroleum pitch
摘要
Abstract
The stabilization, carbonization and graphitization processes in the preparation of isotropic and anisotropic pitch fibers were studied by elemental analysis, TG, DSC, FT-IR, XRD and STM. The reaction mechanisms were deduced and kinetics parameters evaluated. The change of mechanical properties and crystalline parameters during graphitization were also obtained. Results show that the optimum oxygen content for isotropic pitch The d002, Lc, La of isotropic pitch based graphite fibers (IPGF) are 0.3432,3.432 and 8.053nm respectively, while for anisotropic pitch based graphite fibers (APGF) they are 0.3391, 25.69 and 3.05nm.Tensile strength and modulus are respectively 596MPa and 58GPa for IPGF,and 2956MPa and 632GPa for APGF.关键词
沥青纤维/不熔化机理/微观结构Key words
Pitch fibers/Stabilization reaction mechanism/Microstructure分类
化学化工引用本文复制引用
沈曾民,迟伟东,张学军,常维璞..石油沥青基炭纤维的制备[J].新型炭材料,2005,20(1):1-7,7.基金项目
国家高技术发展863计划项目. ()