中山大学学报(自然科学版)2007，Vol.46Issue(z1)：17-18,2.
偏硼酸钠与镁和氢反应的硼氢化钠生成
NaBH4 Formation Through NaBO2 Reacts with Mg and H2
摘要
Abstract
The effects of temperature, hydrogen pressure and catalyst addition on sodium borohydride formation were investigated. Higher H2 pressure is of benefit to NaBH4 formation. Increasing reaction temperature can improve NaBH4 formation kinetic property. However, if the temperature is near the melting point of Mg, the NaBH4 formation was impeded. Ni, Fe and Co addition in the H2+Mg+NaBO2 system promoted the NaBH4 formation, but Cu addition showed a negative effect.关键词
硼氢化钠生成/动力学特性/催化剂/反应温度/氢压Key words
sodium borohydride formation/ kinetic property, catalyst/ reaction temperature/ hydrogen pressure.分类
信息技术与安全科学引用本文复制引用
刘宾虹,李洲鹏,朱京科..偏硼酸钠与镁和氢反应的硼氢化钠生成[J].中山大学学报(自然科学版),2007,46(z1):17-18,2.基金项目
国家863计划资助项目(2006AA05Z120) （2006AA05Z120）
