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高温热曝露对3D-C/SiC复合材料弯曲性能的影响

侯军涛 乔生儒 张程煜 张跃冰

新型炭材料2009,Vol.24Issue(2):173-177,5.
新型炭材料2009,Vol.24Issue(2):173-177,5.DOI:10.1016/S1872-5805(08)60046-3

高温热曝露对3D-C/SiC复合材料弯曲性能的影响

The influence of high temperature exposure to air on the damage to 3D-C/SiC composites

侯军涛 1乔生儒 1张程煜 1张跃冰2

作者信息

  • 1. 西北工业大学,超高温结构复合材料实验室,陕西,西安,710072
  • 2. 哈尔滨工业大学,金属精密热加工国家级重点实验室,黑龙江,哈尔滨,150001
  • 折叠

摘要

Abstract

3D-C/SiC composites, exposed in air at 600, 900, and 1 300 ℃ for 0 to 15 h, were investigated by three point bend tests at room temperature, SEM, and energy dispersive spectroscopy. The results show that the damage curves, expressed as a relative change of elastic modulus, of the composites for a 15h exposure, could be divided into a sharply increasing stage (stage Ⅰ) and a steady increasing stage ( stage Ⅱ). Stage Ⅰ may be caused by a direct oxidation of the carbon fibers and interface carbon layers by the oxygen in air, and stage Ⅱ may be caused by a diffuse controlled oxidation of the inner part of the composites. The matrix micro-cracks, induced by a difference of coefficients of thermal expansion between matrix and carbon fibers in the cooling process after composite preparation act as oxygen diffuse paths and are where the oxidation takes place. The fact that the damage decreases with temperature for the same exposure time may be caused by the crack shrinking at high temperature, which decreases the oxidizable surface area and inhibits the diffusion of oxygen into the composites.

关键词

3D-C/SiC/热曝露/损伤/弯曲性能

Key words

3D-C/SiC/Thermo-exposure/Damage/Flexural behaviors

分类

通用工业技术

引用本文复制引用

侯军涛,乔生儒,张程煜,张跃冰..高温热曝露对3D-C/SiC复合材料弯曲性能的影响[J].新型炭材料,2009,24(2):173-177,5.

基金项目

国家重点实验室金属精密热加工基金,长江学者和创新团队发展计划项目资助.Foundation of National Key Laboratory for Precision Hot Processing of Metals and Program for Changjiang Scholars and Innova-tive Research Team in University ()

新型炭材料

OA北大核心CSCDCSTPCDSCI

1007-8827

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