燃料化学学报2001，Vol.29Issue(2)：174-176,3.
甲醇水蒸气重整制氢独立反应探讨
ANALYSIS OF INDEPENDENT REACTIONS INKINETIC MODEL OF METHANOL-STEAM REFORMING PROCESS
摘要
Abstract
Different routes of methanol-steam reforming over ZnO-Cr2O3 catalyst have been discussed. There are two independent reactions with five components and three elements in this process . Using the parameter defined as the difference between the real temperature and pseudo thermodynamic equilibrium temperature based on the value of PcoPH2o/Pco2 PH2 in the outflow, our calculations of experimental data showed that neither the water-gas shift reac tion nor its reverse reaction is proper to appear in the kinetic model. The reasonable model may be represented by parallel reaction model, taking SRM and DE as the independent reactions. Therefore the two components of CO and CO2 are produced simultaneously.关键词
动力学/水蒸气重整/甲醇/氢源/燃料电池分类
化学化工引用本文复制引用
王胜年,洪学伦,王树东,吴迪镛..甲醇水蒸气重整制氢独立反应探讨[J].燃料化学学报,2001,29(2):174-176,3.
