物理化学学报2008，Vol.24Issue(11)：1945-1949,5.
[(n-C16-H33)N(CH3)3]2[TiF6]·2H2O的合成、结构和热稳定性
Synthesis, Structure and Thermal Property of [(n-C16H33N)N(CH3)3]2[TiF6]·2H2O
摘要
Abstract
A new compound dicetyltrmethylammonium hexafluorotitanium dihydrate, [(n-C16H33)N(CH3)3]2[TiF6]· 2H2O (compound 1), was hydrothermally synthesized at 150℃ and characterized by single crystal X-ray diffraction, Fourier-transform infrared (FTIR) spectroscopy, elemental analysis, and thermogravimetric analysis. Compound 1 crystallizes in the monoclinic system, space group C2/c. It consists of hexafluorotitanium cations [TiF6]2-, water molecular (H2O), and cetyltrimethylammonium ions [(n-C16H33)N(CH3)3]+, which are connected together by extensive hydrogen bonding.关键词
氟钛酸盐/十六烷基三甲基胺/水热反应Key words
Titanium fluoride/Cetyltrimethylammonium/Hydrothermal reaction分类
化学化工引用本文复制引用
刘国奇,李国宝,廖复辉,林建华..[(n-C16-H33)N(CH3)3]2[TiF6]·2H2O的合成、结构和热稳定性[J].物理化学学报,2008,24(11):1945-1949,5.基金项目
国家自然科学基金(20771008)资助项目 （20771008）
