含能材料2009，Vol.17Issue(2)：198-201,4.DOI:10.3969/j.issn.1006-9941.2009.02.017
高氯酸碳酰肼盐与硝酸碳酰肼盐系列化合物的晶格能与感度性能关系
Relationship between Lattice Energy and Sensitivity of [M(CHZ)3](NO3)2 and [M(CHZ)3](ClO4)2 (M=Mn, Zn, Ni)
郑秋雨 1乔小晶 1邵风雷 1张建国 1杨利1
作者信息
- 1. 北京理工大学,爆炸科学与技术国家重点实验室,北京,100081
- 折叠
摘要
Abstract
The standard molar enthalpies of series of energetic coordination compounds solution with carbohydrazide as ligand and nitrate or perchlorate as anion in deionized water were measured by a Setaram C80II microcalorimeter at 298.15 K. Based on these values, their lattice energy were calculated through Kapustinkii formula, meanwhile the thermochemistry radius of [M(CHZ)3]2+ (M=Mn, Zn, Ni) was gained. The relationship between lattice energy and impact sensitivity or friction sensitivity was discussed. Results show that the lattice energy of perchlorate are smaller than their corresponding nitrate, thus the perchlorate are more sensitive.关键词
物理化学/[M(CHZ)3](NO3)2/[M(CHZ)3](ClO4)2(M=Mn,Zn,Ni)/溶解焓/晶格能/感度Key words
physical chemistry/[M(CHZ)3](NO3)2/[M(CHZ)3](ClO4)2 (M=Mn, Zn, Ni)/enthalpy of solution/lattice energy/sensitivity分类
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郑秋雨,乔小晶,邵风雷,张建国,杨利..高氯酸碳酰肼盐与硝酸碳酰肼盐系列化合物的晶格能与感度性能关系[J].含能材料,2009,17(2):198-201,4.
