感光科学与光化学2003，Vol.21Issue(1)：20-24,5.
硅胶固载光敏剂的合成及其在反式维生素D3光敏异构化为顺式维生素D3中的应用
SYNTHESIS OF SILICA-ANCHORED SENSITIZER AND ITS APPLICATION IN THE PHOTOISOMERIZATION OF trans-VITAMIN D3 TO cis-VITAMIN D3
摘要
Abstract
9-Anthracenemethanol was anchored on silica gel using malonic acid as linker.The photoisomerization of trans-vitamin D3 to cis-vitamin D3 was carried out with this heterogeneous photosensitizer in ethanol and toluene solutions.The experiment results demonstrate that this solid photosensitizer is efficient for the photoisomerization and easy for separated from the reaction mixtures.关键词
光敏异构化反应/固相光敏剂/维生素D3Key words
photoisomerization/solid phase sensitizer/vitamin D3分类
化学化工引用本文复制引用
高云燕,游长江,陈金平,李嫕..硅胶固载光敏剂的合成及其在反式维生素D3光敏异构化为顺式维生素D3中的应用[J].感光科学与光化学,2003,21(1):20-24,5.基金项目
This work was supported by the Ministry of Science and Technology of China(Grant No.G2000078100),the National Science Foundation of China(No.20172059)and Chinese Academy of Sciences. （Grant No.G2000078100）
