含能材料2005，Vol.13Issue(4)：211-213,3.
缩水甘油硝酸酯的一锅法合成
One-pot Synthesis of Glycidyl Nitrate
邱少君 1甘孝贤 2樊慧庆1
作者信息
- 1. 西北工业大学,材料学院,陕西,西安,710072
- 2. 西安近代化学研究所,陕西,西安,710065
- 折叠
摘要
Abstract
A mild, low cost synthetic method of glycidyl nitrate is developed via so called one-pot procedure. Epichlorohydrin added dropwise to the dilute nitric acid (35 wt%) resulted in ring-opening reaction at about 20 ℃. Ring-closing occurred then by the addition of aqueous sodium hydroxide. Glycidyl nitrate was obtained in moderate yield (60%) and its structure was characterized by Fourier transform infrared spectroscopy, hydrogen and carbon nuclear magnetic resonance and elemental analysis.关键词
有机化学/含能材料/合成/缩水甘油硝酸酯/一锅法Key words
organic chemistry/energetic material/synthesis/glycidyl nitrate/one-pot synthesis分类
军事科技引用本文复制引用
邱少君,甘孝贤,樊慧庆..缩水甘油硝酸酯的一锅法合成[J].含能材料,2005,13(4):211-213,3.
