华东理工大学学报(自然科学版)2001,Vol.27Issue(2):214-216,3.
过碳酸钠的热分解反应动力学
Thermal Decomposition Reaction Kinetics of Sodium Percarbonate
摘要
Abstract
The kinetic characteristic parameter of thermal decomposition of sodium percarbonate with/without stabilizer are calculated according to the Coats and Redfern's linearized simple graphical procedure. It is shown that the reaction order is 0.2; the activation energies are 183.9 kJ/mol and 162.5kJ/mol and the frequency factors are 2.15×1020s-1 and 9.12×1018s-1 respectively. The higher stability of sodium percarbonate with stabilizer is affirmed by kinetic parameters.
关键词
过碳酸钠/稳定性/反应动力学/反应级数/活化能分类
化学化工引用本文复制引用
秦付云,顾达..过碳酸钠的热分解反应动力学[J].华东理工大学学报(自然科学版),2001,27(2):214-216,3.