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Adsorption Kinetics of Methylene Blue from Aqueous Solutions onto Palygorskite

PENG Shuchuan WANG Shisheng CHEN Tianhu JIANG Shaotong HUANG Chuanhui

地质学报(英文版)2006,Vol.80Issue(2):236-242,7.
地质学报(英文版)2006,Vol.80Issue(2):236-242,7.

Adsorption Kinetics of Methylene Blue from Aqueous Solutions onto Palygorskite

Adsorption Kinetics of Methylene Blue from Aqueous Solutions onto Palygorskite

PENG Shuchuan 1WANG Shisheng 2CHEN Tianhu 1JIANG Shaotong 1HUANG Chuanhui3

作者信息

  • 1. School of Resources and Environmental Engineering, Hefei University of Technology, Heifei, Anhui 230009
  • 2. Department of Soil Chemistry and Environmental Protection, Institute of Soil Science, Chinese Academy of Sciences, Nanjing, Jiangsu 210008
  • 3. Department of Chemistry, University of Sciences and Technology of China, Heifei, Anhui 230009
  • 折叠

摘要

Abstract

The adsorption kinetics of methylene blue from aqueous solutions on purified palygorskite was investigated. The kinetics data related to the adsorption of methylene blue from aqueous solutions are in good agreement with the pseudo-second order equation in ranges of initial concentration of 120-210 mg/L, oscillation speed of 100-200 r/min and temperature of 298-328K. The experimental results show that methylene blue is only adsorbed onto the external surface of purified palygorskite,and the apparent adsorption activation energy is 13.92 k J/mol. The relatively low apparent adsorption activation energy suggests that the adsorption of methylene blue involves in not only a chemical, but also a physical adsorption process, and it is controlled by the combination of chemical adsorption and liquid-film diffusion.

关键词

purified palygorskite/adsorption/methylene blue/kinetics

Key words

purified palygorskite/adsorption/methylene blue/kinetics

分类

天文与地球科学

引用本文复制引用

PENG Shuchuan,WANG Shisheng,CHEN Tianhu,JIANG Shaotong,HUANG Chuanhui..Adsorption Kinetics of Methylene Blue from Aqueous Solutions onto Palygorskite[J].地质学报(英文版),2006,80(2):236-242,7.

基金项目

Financial supports from National Natural Science Foundation of China (No. 40472026 and No. 40072017)are gratefully acknowledged. (No. 40472026 and No. 40072017)

地质学报(英文版)

1000-9515

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