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调质钙基脱硫剂硫化特性研究

王春波 陈鸿伟 吉云

中国电机工程学报2004,Vol.24Issue(12):238-242,5.
中国电机工程学报2004,Vol.24Issue(12):238-242,5.

调质钙基脱硫剂硫化特性研究

INVESTIGATION ON SULFATION OF MODIFIED CA-BASED SORBENT

王春波 1陈鸿伟 1吉云1

作者信息

  • 1. 华北电力大学能源与动力工程学院,河北省,保定市,071003
  • 折叠

摘要

Abstract

The sulfation of a limestone modified by additives was investigated which aimed to find the causes of its enhanced sulfation capacity. A new mechanism to explain M-CaO (calcined from modified limestone) sulfation is suggested: more lattice defects are formed in M-CaO, which reduce the resistance of ion diffusion in the CaSO4 product layer, and increase the Ca-conversion. To find the further facts to support this theory, the element distribution in reacted M-CaO and the pore structure of CaO were measured. A conclusion about how lattice defects were formed in the product layers was drawn.

关键词

热力工程/调质钙基脱硫剂/硫化/孔结构/产物层/离子扩散/晶格缺陷

Key words

Thermal power engineering/Modified Ca-based sorbent/Sulfation/Pore/Product layer/Ion diffusion/Lattice defects

分类

能源科技

引用本文复制引用

王春波,陈鸿伟,吉云..调质钙基脱硫剂硫化特性研究[J].中国电机工程学报,2004,24(12):238-242,5.

中国电机工程学报

OA北大核心CSCDCSTPCD

0258-8013

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