高等学校化学学报2001，Vol.22Issue(2)：240-244,5.
糖与非电解质在甲酰胺中相互作用的Gibbs自由能参数
Interaction Parameters of the Excess Gibbs Free Energy Between Saccharides and Non-electrolytes in Formamide
摘要
Abstract
The retention values of ten non-electroltyes in stationary solution of formamide-glucose, formamide-fructose and formamide-sucrose at 298.15 K were measured by a gas-liquid chromatographic method(GLC). Depending on the McMillan-Mayer theory, the values of pair and triplet interaction parameters gij and gijj of saccharides with non-electroltyes have been evaluted. The group interaction Gibbs free energy parameters Gx,y were evaluted by the Okamoto-Wood group additivity method. The information about the solute-solute interaction and the effect of solvent were discussed.关键词
Gibbs自由能相互作用参数/基团加合/气液色谱法/糖/非电解质/甲酰胺分类
化学化工引用本文复制引用
汤清虎,白同春,卢雁,赵培真,卢锦梭..糖与非电解质在甲酰胺中相互作用的Gibbs自由能参数[J].高等学校化学学报,2001,22(2):240-244,5.基金项目
国家自然科学基金 （）
