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咪唑啉衍生物在含CO2的模拟深层气井水溶液中缓蚀机理

陆原 刘鹤霞 赵景茂

电化学2007,Vol.13Issue(3):242-248,7.
电化学2007,Vol.13Issue(3):242-248,7.

咪唑啉衍生物在含CO2的模拟深层气井水溶液中缓蚀机理

Inhibition Mechanism of Imidazoline Derivate in Simulated Water from Deep Gaswell Containing CO2

陆原 1刘鹤霞 1赵景茂1

作者信息

  • 1. 北京化工大学材料科学与工程学院,北京,100029
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摘要

Abstract

The electrochemical method and atomic force microscope (AFM) were applied to study the inhibition mechanism of Im-D, an imidazoline derivate inhibitor, for mild steel in CO2 saturated solution. The imidazoline derivate can inhibit effectively CO2 corrosion, make the steel surface smoother and belongs to the anodic controlled mixed-type inhibitor. Its adsorption on the surface of mild steel is a spontaneous and exothermic process accompanied by the decrease of entropy and follows the Langmuir adsorption isothermal equation. The lower temperature will facilitate the process. The changes in the apparent activation energy (Ea) and the pre-exponential factor (A) of the corrosion reaction before and after the addition of inhibitor were also discussed.

关键词

CO2腐蚀/缓蚀剂/咪唑啉衍生物/AFM/Langmiur吸附

Key words

CO2 corrosion/ inhibitor/ imidazoline derivate/ AFM/ Langmiur adsorption

分类

化学化工

引用本文复制引用

陆原,刘鹤霞,赵景茂..咪唑啉衍生物在含CO2的模拟深层气井水溶液中缓蚀机理[J].电化学,2007,13(3):242-248,7.

电化学

OA北大核心CSCDCSTPCD

1006-3471

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