材料科学与工程学报2006，Vol.24Issue(1)：25-28,4.
3,3',5,5'-四甲基联苯胺与钼磷酸纳米晶分子杂化材料的合成与表征
Synthesis and Characterization of Nano-Crystals Molecular Hybrid Material with 3,3',5,5'-Tetramethylbenzidine and Molybdophosphate
摘要
Abstract
A novel nano-crystal molecular hybrid material has been synthesized with 3,3',5,5'-tetramethylbenzidine (short for TMB) and Keggin structure heteropoly acid H3PMo12O40. The formula of this hybrid material was characterized to be (TMB)3 PMo12O40. TEM images showed that the organic-inorganic hybrid material is a nano-crystal in size of 40～60nm. IR, UV-vis and ESR spectra indicate that there is strong electron interaction between TMB and molybdophosphate forming a charge-transfer supermolecule hybrid material, which shows significant photosensitive and electrocatalytic properties.关键词
纳米晶/分子杂化材料/电荷转移/钼磷酸/3,3',5,5'-四甲基联苯胺Key words
nano-crystal/molecular hybrid material/charge-transfer/molybdophosphate/3,3',5,5'-Tetramethylbenzidine分类
通用工业技术引用本文复制引用
吴莹,闻荻江,徐玲,王振平..3,3',5,5'-四甲基联苯胺与钼磷酸纳米晶分子杂化材料的合成与表征[J].材料科学与工程学报,2006,24(1):25-28,4.基金项目
This work was financially supported by the National Natural Science Foundation of China (20275025) and the Natural Science Foundation of Jiangsu committee of Education (05KJB150123). （20275025）
