含能材料2006，Vol.14Issue(4)：257-261,5.
5-硝基间苯二甲酸锰配合物的合成、晶体结构和热分解研究
Synthesis, Crystal Structure and Thermal Behavior of 5-Nitroisophthalate Complex with Mn(Ⅱ)
摘要
Abstract
The crystal of the title complex Mn(nip)(H2O)5 ( nip=5-nitroisophthalate ) was synthesized, and cultured in the filtrate of the reaction mixture. The X-ray single crystal diffractometer with graphite monochromated MoKα (λ= 0.71073(A)), elemental microanalysis, FT-IR, DSC and TG-DTG techniques were used to characterize the structure and thermal behaviors of the title complex. The results show that the central Mn2+ cation coordinates to the ligands 5-nitroisophthalate and 5H2O in a distorted octahedral pattern. And the title coordination compound loses its five water molecules at the first step and the 5-nitroisophthalate at the second step during heating based on the thermal analyses and FT-IR data.关键词
分析化学/Mn(nip)(H2O)5/配位化合物/晶体结构/热分解Key words
analytical chemistry/Mn(nip)(H2O)5/complex/crystal structure/thermal decomposition分类
通用工业技术引用本文复制引用
郭金玉,张同来,张建国,刘艳红,郁开北..5-硝基间苯二甲酸锰配合物的合成、晶体结构和热分解研究[J].含能材料,2006,14(4):257-261,5.基金项目
The National Natural Science Foundation of China(20471008) and The Fundamental Research Foundation Beijing Institute of Technology(BIT-UBF-200302B01 & BIT-UBF-200502B4221). （20471008）
