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超声场对碳酸钙反应结晶成核影响的研究

杭方学 卢群 丘泰球 姚成灿

陕西科技大学学报(自然科学版)2007,Vol.25Issue(1):26-31,6.
陕西科技大学学报(自然科学版)2007,Vol.25Issue(1):26-31,6.

超声场对碳酸钙反应结晶成核影响的研究

EFFECT OF ULTRASOUND ON THE NUCLEATION OF CALCIUM CARBONATE DURING REACTIVE CRYSTALLIZATION

杭方学 1卢群 2丘泰球 3姚成灿1

作者信息

  • 1. 华南理工大学轻工研究所,广东,广州,510640
  • 2. 广西大学轻工与食品工程学院,广西,南宁,530004
  • 3. 广东药学院,广东,广州,510224
  • 折叠

摘要

Abstract

The effect of ultrasound on reactive crystallization is studied by measuring the induction time. Calcium carbonate is used as the working substance precipitated by mixing CaCl2 and Na2CO3/NaHCO3 solutions. The experiments were carried with various frequencies and insonation time. It is observed that the induction time significantly decreases with increasing insonation time. The mechanismof the ultrasonic effect on nucleation is analyzed.The two effects of ultrasound are discussed. The surface tension (γ) decreased and the diffusion coefficient (DAB) increased in the ultrasound. The induction time reduced after ultrasound treating.

关键词

超声场/诱导期/结晶/成核

Key words

ultrasound/ induction time/ crystallization/ nucleation

分类

轻工纺织

引用本文复制引用

杭方学,卢群,丘泰球,姚成灿..超声场对碳酸钙反应结晶成核影响的研究[J].陕西科技大学学报(自然科学版),2007,25(1):26-31,6.

基金项目

广东省自然科学基金(980534),广东省重点科技项目(99M02002G) (980534)

陕西科技大学学报(自然科学版)

OACSTPCD

2096-398X

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