电化学2004，Vol.10Issue(3)：271-278,8.
对甲苯磺酸铜及其配合物电化学行为研究
Studies on the Electrochemical Behavior of Copper Paratolysulfate and its Complexes
摘要
Abstract
Copper (II) paratolysulfate has been synthesized and characterized by thermo-gravimetric (TG) measurements and differential scanning calorimetric (DSC) analysis. This salt can easily lose all crystal water and the dehydrated salt does not deliquesce in the air. It is found for the first time that the complex of Cu(p-OTs)2/ethanolamine(1∶ 1) can catalyze the oxidation of 1,1′-bi-2-naphthol in DMSO and DMF, while the process is difficult to perform in H2O and CH3OH. The electrochemical behaviors of both Cu(p-OTs)2 and its complexes with ethanolamine have been studied on platinum electrode in DMSO, DMF, CH3OH and H2O respectively. The complexes of various copper salts with ethanolamine are also studied by cyclic voltammetry in different solvents. It is concluded that the two one-electron steps are essential condition for the oxidation of 1,1′-bi-2-naphthol.关键词
对甲苯磺酸铜/模拟酶/电化学/1,1′-联-2-萘酚Key words
Copper paratolysulfate, Mimetic enzyme, Electrochemistry, 1,1′-bi-2-naphthol分类
化学化工引用本文复制引用
宋继国,沈培康..对甲苯磺酸铜及其配合物电化学行为研究[J].电化学,2004,10(3):271-278,8.基金项目
Guandong Province Project(2003B12006,013024), Guangzhou Science and Technology Project (2003Z2-D0081) supported （2003B12006,013024）
