应用化学2001，Vol.18Issue(4)：272-275,4.
2，5-二甲氧基苯胺的乳液聚合及聚合物结构表征
The Emulsion Polymerization of 2,5-Dimethoxyaniline and The Characterization of Polymer Structure
摘要
Abstract
The effects of temperature, concentrations of initiator(KPS) and emulsifier(SDS) on emul-sion polymerization of 2,5-dimethoxyaniline (DMAn) were investigated. The polymer PDMAn withnumber-average molecualr weight of 1.22×104 was obtained in the conditions, [-monomer] = 6. 0 ×10-3 mol/L, [SDS]≥5.0×10-2 mol/L, [KPS]=3.5×10-3 mol/L, 85 ℃, for 2.0 h. 1H NMR,FTIR and TEM techniques were used in structure characterization, the results showed that the poly-mer was produced by ara-polymerization and the ratio of benzoid to quinoid units was 3: 1 in its
macromolecular chain.关键词
聚二甲氧基苯胺/乳液聚合/聚合物结构分类
化学化工引用本文复制引用
戴李宗,许一婷,邹友思,吴辉煌..2，5-二甲氧基苯胺的乳液聚合及聚合物结构表征[J].应用化学,2001,18(4):272-275,4.
