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碳钢在NaHCO3溶液中的阳极极化行为

赵景茂 左禹

电化学2005,Vol.11Issue(1):27-31,5.
电化学2005,Vol.11Issue(1):27-31,5.

碳钢在NaHCO3溶液中的阳极极化行为

Anodic Polarization Behaviors of Carbon Steel in Bicarbonate Solution

赵景茂 1左禹1

作者信息

  • 1. 北京化工大学材料科学与工程学院,北京,100029
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摘要

Abstract

The anodic polarization curves of mild steel were measured in sodium bicarbonate solution of various concentrations, and the surface products were analyzed by XPS. Two anodic current peaks and two passive zones are observed in all the curves. When HCO3- ions concentration is below 0.1mol/L, the two peaks are so close that the first passive zone is difficult to be observed. When HCO3- ions concentration is above 0.1 mol/L, the first peak appears clear, while the second becomes smaller. The XPS results indicate that the out layer of film formed at a higher potential is mainly composed of Fe2O3, and the inner film is a mixture of ferrous and ferric oxide.

关键词

阳极极化/碳钢/NaHCO3溶液

Key words

Anodic polarization/Carbon steel/Bicarbonate solution

分类

矿业与冶金

引用本文复制引用

赵景茂,左禹..碳钢在NaHCO3溶液中的阳极极化行为[J].电化学,2005,11(1):27-31,5.

基金项目

Financially suported by the National Natural Science Foundation (Contract 50271005) (Contract 50271005)

电化学

OA北大核心CSCD

1006-3471

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