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锂离子电池负极材料纳米Ni3Sn2的溶剂热合成与电化学性能

秦海英 赵新兵 李洲鹏

中山大学学报(自然科学版)2007,Vol.46Issue(z1):274-275,280,3.
中山大学学报(自然科学版)2007,Vol.46Issue(z1):274-275,280,3.

锂离子电池负极材料纳米Ni3Sn2的溶剂热合成与电化学性能

Solvothermal Synthesis and Electrochemical Performance of Nano-Ni3Sn2 Used as Anodes for Lithium-ion Batteries

秦海英 1赵新兵 2李洲鹏1

作者信息

  • 1. 浙江大学化学与生物工程系,浙江,杭州,310027
  • 2. 浙江大学材料科学与工程系,浙江,杭州,310027
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摘要

Abstract

A nano-Ni3Sn2 intermetallic compound was prepared by solvothermal method for an anode material of lithium-ion batteries. The samples were characterized by X-ray diffraction (XRD) and field emission scanning electron microscopy (FESEM). The electrochemical performances of the materials were evaluated by galvanostatic charge and discharge cycling in a lithium-ion model cell Li/LiPF6(EC+DMC)/ Ni3Sn2. It was found that the first delithiation capacity of nano-Ni3Sn2 was 136 mAh·g-1. The annealed Ni3Sn2 electrodes exhibited a better capacity retention compared to the unannealed Ni3Sn2 electrodes.

关键词

锂离子电池/负极/Ni3Sn2/溶剂热合成/电化学性能

Key words

lithium-ion batteries/anodes/Ni3Sn2/solvothermal synthesis/electrochemical performances

分类

矿业与冶金

引用本文复制引用

秦海英,赵新兵,李洲鹏..锂离子电池负极材料纳米Ni3Sn2的溶剂热合成与电化学性能[J].中山大学学报(自然科学版),2007,46(z1):274-275,280,3.

基金项目

国家863计划资助项目(2006AA05Z120) (2006AA05Z120)

中山大学学报(自然科学版)

OA北大核心CSCDCSTPCD

0529-6579

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