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超级电容器用聚苯胺/活性炭复合电极的研究

王琴 李建玲 高飞 李文生 武克忠 王新东

新型炭材料2008,Vol.23Issue(3):275-280,6.
新型炭材料2008,Vol.23Issue(3):275-280,6.

超级电容器用聚苯胺/活性炭复合电极的研究

Activated carbon coated with polyaniline as an electrode material in supercapacitors

王琴 1李建玲 1高飞 1李文生 2武克忠 1王新东1

作者信息

  • 1. 北京科技大学理化系,北京,100083
  • 2. 锦州凯美能源有限公司,辽宁,锦州,121000
  • 折叠

摘要

Abstract

The performance of activated carbons coated with polyaniline (PANI-C) by polymerization of aniline using cyclic voltammetry was investigated as an electrode for supercapacitors by scanning electron microscopy, electrochemical impedance spectroscopy, and constant current charge/discharge measurement. Results showed that a PANI thin film was uniformly deposited on the surface of the activated carbon, forming an interlinked porous network. The PANI-C compos-ite electrodes had better cycling stability than PANI electrodes and the specific capacitance of the composite electrodes was 587 F/g, which was much higher than that of the pristine activated carbon ( 140F/g), owing to the faradic reaction of PANI with the electrolyte. The PANI electrode was less stable than the PANI-C composite electrode with a capaci-tance decay from 513 to 334F/g for the former and 415 to 385 for the latter, after 50cycles.

关键词

超级电容器/聚苯胺/活性炭/循环伏安/比电容

Key words

Supercapacitor/Polyaniline/Activated carbon/Cyclic voltammetry/Specific capacitance

分类

化学化工

引用本文复制引用

王琴,李建玲,高飞,李文生,武克忠,王新东..超级电容器用聚苯胺/活性炭复合电极的研究[J].新型炭材料,2008,23(3):275-280,6.

基金项目

国家"863"计划资助项目(2005AA501560).The National High-Technology Research and Development Program ( "863" Program) of China (2005AA501560). (2005AA501560)

新型炭材料

OA北大核心CSCDCSTPCD

1007-8827

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