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掺镁近化学计量比铌酸锂晶体的生长

姚淑华 王继扬 刘宏 胡小波 张怀金 吴剑波 秦晓勇

硅酸盐学报2007,Vol.35Issue(3):281-284,4.
硅酸盐学报2007,Vol.35Issue(3):281-284,4.

掺镁近化学计量比铌酸锂晶体的生长

GROWTH AND CHARACTERISTICS OF MAGNESIUM-DOPED NEAR-STOICHIOMETRIC LITHIUM NIOBATE CRYSTAL

姚淑华 1王继扬 1刘宏 1胡小波 1张怀金 1吴剑波 2秦晓勇2

作者信息

  • 1. 山东大学,晶体材料国家重点实验室,济南,250100
  • 2. 中电科技德清华蓥电子有限公司,德清,313200,浙江
  • 折叠

摘要

Abstract

An magnesium(MgO)-doped near-stoichiometric lithium niobate crystal(MgO:SLN) of 40 mm in diameter and 60 mm in length was grown by an improved Czochralski technique from a 58.5% (in molar fraction,the same below) Li melt doped with 2% MgO in a platinum crucible.The concentration of Nb5+ and Mg2+ in the growth crystal was measured by X-ray fluorescence.The defects structure of MgO:SLN was investigated by ultraviolet absorption spectra and infrared absorption spectra.The MgO:SLN crystal exhibited a shorter absorption edge wavelength.and the OH- infrared absorption band showed that the MgO doping concentration of the MgO:SLN crystal exceeded the optical damage resistance threshold concentration.The specific heat capacity of the crystal was measured to be 0.69 J/(g·K) and was higher than that of congruent LiNbO3(CLN) crystal 0.64 J/(g·K).

关键词

掺镁铌酸锂晶体/近化学计量比/提拉法

Key words

magnesium-doped lithium niobate crystal/near-stoichiometric/Czochralski method

分类

数理科学

引用本文复制引用

姚淑华,王继扬,刘宏,胡小波,张怀金,吴剑波,秦晓勇..掺镁近化学计量比铌酸锂晶体的生长[J].硅酸盐学报,2007,35(3):281-284,4.

基金项目

国家基础研究计划(2004CB619002)助项目. (2004CB619002)

硅酸盐学报

OA北大核心CSCDCSTPCD

0454-5648

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