含能材料2004，Vol.12Issue(5)：282-286,5.
[Cd(CHZ)3](ClO4)2的快速热分解过程研究
Study on Rapid Thermolysis of [ Cd( CHZ)3 ] ( ClO4 )2
孙远华 1张同来 1马桂霞 1张建国 1伍涛1
作者信息
- 1. 北京理工大学爆炸灾害预防与控制国家重点实验室,北京,100081
- 折叠
摘要
Abstract
To investigate the thermal decomposition behavior of [ Cd(CHZ) 3 ] ( ClO4 )2 (CdCP) ,the Tjump/FT-IR spectroscopy was used to determine the main gaseous products evolved from the thermolysis of sures. With the help of rapid scanning Fourier transform infrared FT-IR spectroscopy, 11 IR-active gas products were resolved during the flash pyrolysis process. The change curves of the concentration of the main gaseous products vs. time were given,indicating that over the range of pressure from 1.0 to 15 atm,the thermal decomposition behavior of CdCP does not seem to be obviously affected by the pressure.关键词
分析化学/高氯酸镉/碳酰肼/快速热分解/T-jump/FT-IRKey words
analytical chemistry/cadmium perchlorate/carbohydrazide/rapid thermolysis/T-jump/FT-IR分类
化学化工引用本文复制引用
孙远华,张同来,马桂霞,张建国,伍涛..[Cd(CHZ)3](ClO4)2的快速热分解过程研究[J].含能材料,2004,12(5):282-286,5.
