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Addition of Ce as additive to Pb-Ca-Sn-Al grid alloy for lead acid battery

魏杰 王东田 栾中华 郭强

哈尔滨工业大学学报(英文版)2003,Vol.10Issue(1):28-30,3.
哈尔滨工业大学学报(英文版)2003,Vol.10Issue(1):28-30,3.

Addition of Ce as additive to Pb-Ca-Sn-Al grid alloy for lead acid battery

Addition of Ce as additive to Pb-Ca-Sn-Al grid alloy for lead acid battery

魏杰 1王东田 1栾中华 1郭强2

作者信息

  • 1. Dept. of Applied Chemistry, Harbin Institute of Technology,Harbin 150001,China
  • 2. Lalin Lead-Acid Battery Factory, Wuchang 150223, China
  • 折叠

摘要

Abstract

The study on three Pb-Ca-Sn-Al alloys with 0.08%, 0.4% and 1.0% of Ce indicates that the addition of Ce results in an obvious increase in the tensile strength and hardness of the alloys, an increase in the overpotentials of hydrogen and oxygen evolution and the corrosion resistance as well. The study on the corrosion film formed on the alloys by cyclic voltammetry shows that the addition of Ce slows down the formation of corrosion film. It is therefore concluded from the experimental results that the addition of Ce can increase the tensile strength and HB of Pb-Ca alloy and the tensile strength and HB of the alloy increase with the increase of Ce; the addition of Ce also increases the hydrogen and oxygen evolution overpotentials of Pb-Ca alloy, and when the content of Ce is 1.0%, the alloy has the highest hydrogen and oxygen evolution overpoteatials; the addition of Ce improves the anticorrosion capability of the alloy, and when the content Ce is 1.0%, the alloy has the best anticorrosion capability; and the addition of Ce also slows down the formation of corrosion film.

关键词

lead-acid battery/grid alloy/Ce/electrochemical performance

Key words

lead-acid battery/grid alloy/Ce/electrochemical performance

分类

信息技术与安全科学

引用本文复制引用

魏杰,王东田,栾中华,郭强..Addition of Ce as additive to Pb-Ca-Sn-Al grid alloy for lead acid battery[J].哈尔滨工业大学学报(英文版),2003,10(1):28-30,3.

基金项目

Sponsored by Postdoctor Startup Fund of Heilongjiang Province(GFCQ 45000045). (GFCQ 45000045)

哈尔滨工业大学学报(英文版)

1005-9113

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