含能材料2009，Vol.17Issue(3)：287-292,6.DOI:10.3969/j.issn.1006-9941.2009.03.009
硝基富勒烯吡咯烷衍生物的合成与结构表征
Synthesis and Characterization of Nitro Fulleropyrrolidine Derivatives
摘要
Abstract
Six nitro fulleropyrrolidine derivatives were synthesized by the 1,3-dipolar cycloaddition reactions of [60]fullerene and the nucleophilic substitution reaction of N-unsubstituted fulleropyrrolidine. The structures of the products were characterized by ultraviolet-visible spectroscopy(UV-Vis), Fourier transform infrared spectrometer(FT-IR), mass spectrometry(MS) and 1H, 13C nuclear magnetic resonance(NMR) techniques. The effects of the different products on the impact sensitivity and friction sensitivity of HMX were tested. The friction and impact sensitivities of HMX reduces from 100% to 48% and to 50%, respectively when 1% N-methyl-2-(3-nitrophenyl)fulleropyrrolidine 2 added in HMX.关键词
有机化学/[60]富勒烯/硝基富勒烯吡咯烷/奥克托今(HMX)/感度Key words
organic chemistry/fullerene/nitro fulleropyrrolidine/HMX/sensitivity分类
军事科技引用本文复制引用
金波,彭汝芳,谭碧生,黄毅民,舒远杰,楚士晋,傅依备..硝基富勒烯吡咯烷衍生物的合成与结构表征[J].含能材料,2009,17(3):287-292,6.基金项目
roject Supported: National Science Fund of China (No.10576026), Sichuan Bureau of Science and Technology (No. 05GG009-018-05), Institute of Chemical Materials, China Academy of Engineering Physics （No.10576026）
