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柠檬酸配比对合成钙钛矿型LaNiO3催化剂结构的影响

王育华 卢星河 佘鸿燕 马楠

中山大学学报(自然科学版)2007,Vol.46Issue(z1):306-307,2.
中山大学学报(自然科学版)2007,Vol.46Issue(z1):306-307,2.

柠檬酸配比对合成钙钛矿型LaNiO3催化剂结构的影响

Study on the Effect of Proportion of Citric Acid to the Structure of Perovskite LaNiO3

王育华 1卢星河 2佘鸿燕 2马楠2

作者信息

  • 1. 天津大学化工学院,天津,300072
  • 2. 河北工程大学,河北,邯郸,056038
  • 折叠

摘要

Abstract

Perovskite LaNiO3 which is used in bifunctional oxygen electrode is prepared by the sol-gel method using citric acid as complexing agent. Products are characterized using TG-DTA, XRD, SEM, et al. It showed that the proportion of citric acid have major influences on cineration of dried polymeric, the structure and component of LaNiO3. Uniformity nanoscaled LaNiO3 bar is got when the proportion of lanthanum nitrate, nickel nitrate and citric acid is between 1∶ 1∶ 0.6 and 1∶ 1∶ 0.7. Furthermore, the effect of sufficient or insufficient proportion of citric acid to the formation and cineration of sol-gel, to the purity of phases and spatial structures of LaNiO3 are discussed.

关键词

LaNiO3/溶胶-凝胶法/柠檬酸/钙钛矿型氧化物

Key words

LaNiO3/sol-gel method/citric acid/perovskite oxides

分类

信息技术与安全科学

引用本文复制引用

王育华,卢星河,佘鸿燕,马楠..柠檬酸配比对合成钙钛矿型LaNiO3催化剂结构的影响[J].中山大学学报(自然科学版),2007,46(z1):306-307,2.

中山大学学报(自然科学版)

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