首页|期刊导航|高技术通讯（英文版）|Preliminary study on electrochemical reduction of carbon dioxide on nickel and platinum electrodes
高技术通讯（英文版）2006，Vol.12Issue(3)：333-336,4.
Preliminary study on electrochemical reduction of carbon dioxide on nickel and platinum electrodes
Preliminary study on electrochemical reduction of carbon dioxide on nickel and platinum electrodes
摘要
Abstract
The electrochemical reduction of carbon dioxide was investigated on nickel and platinum electrodes in 0.5 mol dm-3 KHCO3 solutions. The main products were formic acid and carbon monoxide during the electroreduction of CO2, and the Faradaic efficiency for this process depended on the characteristics of the electrode. At ambient temperature and pressure, the Faradaic efficiency was measured to be 8.6% and 2.5% respectively for the production of formic acid and CO with Pt electrode at -1.3V vs Ag/AgCl (saturated KCl). At this same potential, the Faradaic efficiency was measured to be 8.9% and 1.7%respectively with Ni electrode. Tafel plots showed that the electrochemical reduction of CO2 was not limited by the mass transfer process in the range of -0.8 to -1.2V vs Ag/AgCl (saturated KCl).关键词
electrochemical reduction, CO2, KHCO3 aqueous solution, Ni electrode, Pt electrodeKey words
electrochemical reduction, CO2, KHCO3 aqueous solution, Ni electrode, Pt electrode分类
化学化工引用本文复制引用
Song Shuang,He Zhiqiao,Ye Jiexu,Chen Jianmeng..Preliminary study on electrochemical reduction of carbon dioxide on nickel and platinum electrodes[J].高技术通讯（英文版）,2006,12(3):333-336,4.基金项目
Supported by the National Natural Science Foundation of China (No. 50408024) and Zhejiang Provincial Natural Science Foundation of China (No.M203034). （No. 50408024）
