电化学2004，Vol.10Issue(3)：346-352,7.
硫酸亚铁对化学沉积钴-铁-磷合金中的影响
The Effect of Ferrous Sulphate on the Electroless Deposition of Co-Fe-P Alloys
摘要
Abstract
Electroless deposition of Co-P alloy and Co-Fe-P alloy from an alkaline bath, containing sodium hypophosphite as a reducer, boric acid as a buffer agent and sodium citrate as a complexing agent, was investigated respectively. The effects of process parameters, such as pH of solution and metallic salt mole ratio of CoSO4/FeSO4, on the plating rate were examined. It was found that the presence of ferrous sulfate in the bath has an inhibitory effect on the alloy deposition. As a consequence, the plating rate of Co-Fe-P is lower than that of Co-P. The electrochemical polarization measurements have been carried out to examine the effect of ferrous sulphate on the cathodic or the anodic polarization process. The ferrous sulphate affects both the cathodic and anodic polarization processes, which reduces the deposition current and potential. The results of the electrochemical polarization experiments agree well with those of electroless deposition rate measurements.关键词
化学沉积/合金/钴/铁/电化学极化Key words
Electroless deposition/Alloys/Cobalt/Iron/Electrochemical polarization分类
化学化工引用本文复制引用
王森林,李清华..硫酸亚铁对化学沉积钴-铁-磷合金中的影响[J].电化学,2004,10(3):346-352,7.基金项目
Supported by the Natural Science Foundation of Fujian Province (No. E0210020) （No. E0210020）
